Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
High-grade metamorphism and partial melting in Archean composite grey gneiss complexes
2016
Much of the exposed Archaean crust is composed of composite gneiss which includes a large proportion of intermediate to tonalitic material. These gneiss terrains were typically metamorphosed to amphibolite to granulite facies conditions, with evidence for substantial partial melting at higher grade. Recently published activity–composition (a-x) models for partial melting of metabasic to intermediate compositions allows calculation of the stable metamorphic minerals, melt production and melt composition in such rocks for the first time. Calculated P–T pseudosections are presented for six bulk rock compositions taken from the literature, comprising two metabasic compositions, two intermediate…
Ash-plume dynamics and eruption source parameters by infrasound and thermal imagery: The 2010 Eyjafjallajökull eruption
2013
During operational ash-cloud forecasting, prediction of ash concentration and total erupted mass directly depends on the determination of mass eruption rate (MER), which is typically inferred from plume height. Uncertainties for plume heights are large, especially for bent-over plumes in which the ascent dynamics are strongly affected by the surrounding wind field. Here we show how uncertainties can be reduced if MER is derived directly from geophysical observations of source dynamics. The combination of infrasound measurements and thermal camera imagery allows for the infrasonic type of source to be constrained (a dipole in this case) and for the plume exit velocity to be calculated (54–14…
Abiotic and biotic controls on methane formation down to 2.5 km depth within the Precambrian Fennoscandian Shield
2017
Abstract Despite a geological history characterised by high temperature and pressure processes and organic carbon deprived crystalline bedrock, large amounts of hydrocarbons are found in deep groundwaters within Precambrian continental shields. In many sites, methane comprises more that 80% of the dissolved gas phase reaching concentrations of tens of mmol l −1 . In this study, we used isotopic methods to study the carbon isotope systematics and sources of crustal methane within the Fennoscandian Shield. The main study sites were the Outokumpu Deep Drill Hole and the Pyhasalmi mine in Finland, both of which allow groundwater sampling down to 2.5 km depth and have been previously studied for…
Long-term stability of alpha particle damage in natural zircon
2005
Abstract We report the first discovery of radiation damage haloes generated by alpha particles in zircon. Proterozoic zircon crystals from a potassium-rich leucogranite from the Adirondack Mountains, New York State, have interior regions that are generally low in actinide elements (UO 2 + ThO 2 ≤ 0.02 wt.%) but show a remarkable pattern of heterogeneous metamictisation. The degree of radiation damage in these regions is not uniformly low, as would be expected if it corresponded to the observed actinide distribution patterns and age of the crystals. Rather, radiation damage is significantly increased in the outermost micro-areas of the low-actinide regions. The additional radiation damage …
Numerical evidence for thermohaline circulation reversals during the Maastrichtian
2005
[1] The sensitivity of the Maastrichtian thermohaline circulation to the opening/closing of marine communications between the Arctic and North Pacific oceans is investigated through a set of numerical experiments using the model CLIMBER-2 (Earth Model of Intermediate Complexity). We show here that the opening or closing of an Arctic-Pacific marine gateway induces transitions between different equilibrium states of the thermohaline circulation. Sensitivity tests of the inferred modes of thermohaline circulation to atmospheric CO2 level changes have also been explored. An abrupt switch in deep convection from high northern to high southern latitudes, a change consistent with isotopic evidence…
Determination of water speciation in hydrous haplogranitic glasses with partial Raman spectra
2020
Abstract We use a mathematical approach to decompose the Raman water band at 3000 cm−1 to 3750 cm−1 into two partial Raman spectra corresponding to the individual Raman activity of the two water species, i.e., molecular water (H2Om) and OH-groups, present in hydrous rhyolitic glasses. The approach is based on a least-squares optimization algorithm and the assumption that the water band can be expressed as a linear combination of two partial Raman spectra. Our model makes no assumptions regarding the shape of the partial Raman spectra. The model input consists of about 700 Raman spectra from hydrous haplogranitic (HPG8) compositions with total water contents from 0.6 to 3.1 wt% and with know…
Influence of basement heterogeneity on the architecture of low subsidence rate Paleozoic intracratonic basins (Reggane, Ahnet, Mouydir and Illizi bas…
2018
The Paleozoic intracratonic North African Platform is characterized by an association of arches (ridges, domes, swells, or paleo-highs) and low subsidence rate syncline basins of different wavelengths (75–620 km). The Reggane, Ahnet, Mouydir and Illizi basins are successively delimited from east to west by the Amguid El Biod, Arak-Foum Belrem, and Azzel Matti arches. Through the analysis of new unpublished geological data (i.e., satellite images, well logs, seismic lines), the deposits associated with these arches and syncline basins exhibit thickness variations and facies changes ranging from continental to marine environments. The arches are characterized by thin amalgamated deposi…
Activity-composition relations for the calculation of partial melting equilibria in metabasic rocks
2020
A set of thermodynamic models is presented that, for the first time, allows partial melting equilibria to be calculated for metabasic rocks. The models consist of new activity–composition relations combined with end-member thermodynamic properties from the Holland & Powell dataset, version 6. They allow for forward modelling in the system Na (Formula presented.) O–CaO–K (Formula presented.) O–FeO–MgO–Al (Formula presented.) O (Formula presented.) –SiO (Formula presented.) –H (Formula presented.) O–TiO (Formula presented.) –Fe (Formula presented.) O (Formula presented.). In particular, new activity–composition relations are presented for silicate melt of broadly trondhjemitic–tonalitic compo…
The ~2730 Ma onset of the Neoarchean Yilgarn Orogeny
2017
The timing of the onset of an orogeny is commonly constrained indirectly, because early orogenic structures are rarely exposed, or are overprinted. Establishing the onset of an Archean orogeny is considerably more challenging, because of the more fragmented geological record and the general lack of consensus about Archean geodynamics. We combine existing tectono-stratigraphic data with new structural and geophysical datasets to establish the onset of the Neoarchean Yilgarn Orogeny (Yilgarn Craton, Western Australia). We show that the surface of the c. 2960–2750 Ma deep-marine Yilgarn greenstone sequence was uplifted, eroded and unconformably overlain by a c. 2730 Ma, syntectonic clastic seq…
Marine climate and hydrography of the Coralline Crag (early Pliocene, UK): isotopic evidence from 16 benthic invertebrate taxa
2019
The taxonomic composition of the biota of the Coralline Crag Formation (early Pliocene, eastern England) provides conflicting evidence of seawater temperature during deposition, some taxa indicating cool temperate conditions by analogy with modern representatives or relatives, others warm temperate to subtropical/tropical conditions. Previous isotopic (δ18O) evidence of seasonal seafloor temperatures from serial ontogenetic sampling of bivalve mollusk shells indicated cool temperate winter (<10 °C) and/or summer (<20 °C) conditions but was limited to nine profiles from two species, one ranging into and one occurring exclusively in cool temperate settings at present. We supplement these resu…